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([eta superscript 5]-Cyclopentadienyl)[(1,2,3,4,4a,12a-[eta])-naphtho[2,3-b][1,4]benzodioxine]iron(II) hexafluoridophosphate

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dc.creator Hendsbee, Arthur D.
dc.creator Masuda, Jason Douglas, 1977-
dc.creator Piorko, Adam
dc.date.accessioned 2013-06-17T14:48:13Z
dc.date.available 2013-06-17T14:48:13Z
dc.date.issued 2010-09
dc.identifier.issn 1600-5368
dc.identifier.uri http://library2.smu.ca/xmlui/handle/01/24999
dc.description Publisher's version/PDF
dc.description.abstract At 296 (2) K, both complexed rings in the iron(II) complex cation of the title salt, [Fe(C[subscript 5]H[subscript 5])(C[subscript 16]H[subscript 10]O[subscript 2])]PF[subscript 6], are almost parallel [dihedral angle between planes = 2.4 (3)°]. The quaternary C atoms of the complexed arene ring are located at the longest distance from the Fe atom, with Fe—C distances of 2.112 (4) and 2.105 (3) [Angstrom], which are slightly longer than the average Fe—C distance for this ring (2.083 [Angstrom]). The Fe ion is located 1.660 (1) and 1.543 (1) [Angstrom], respectively, from the cyclopentadienyl and the complexed arene ring.
dc.language.iso en en_CA
dc.publisher International Union of Crystallography
dc.relation.uri http://dx.doi.org/10.1107/S1600536810033179
dc.subject.lcsh Crystallography
dc.subject.lcsh Iron salts
dc.subject.lcsh Organometallic compounds
dc.title ([eta superscript 5]-Cyclopentadienyl)[(1,2,3,4,4a,12a-[eta])-naphtho[2,3-b][1,4]benzodioxine]iron(II) hexafluoridophosphate en_CA
dc.type Text en_CA
dcterms.bibliographicCitation Acta Crystallographica E66, m1154. (2010)

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